Cucurbituril-X
Cucurbit[8]uril

Cucurbit[8]uril

Basic Information

Product NameCucurbit[8]uril
CAS Registry Number259886-51-6
FormulaC48H48N32O16·10H2O
Molecular Weight1508 g/mol
Purity≥98%
StorageSealed, light-proof, store at room temperature in dry conditions

Specifications & Pricing

SpecificationsPriceStock Status
500mg$280In Stock
1g$420In Stock
5g$1,400In Stock
10g$2,520In Stock

Product Description

Solubility: Very poor water solubility (10⁻⁴–10⁻⁵ M). Soluble in strong acids (6 M HCl ~10 mg/mL). Chemical properties: Forms complexes with metal ions and host-guest complexes. Appearance: Colorless or white powder, purity ≥95%.

Applications

Ternary ComplexationSupramolecular PolymersPhotochemistry

Technical notes on CB[8]

CB[8] offers a ≈479 ų cavity with a ≈6.9 Å portal and is best known for binding two guests simultaneously as a 1:1:1 ternary complex — classically an electron acceptor (methyl viologen) paired with an electron donor (naphthol, aromatic amino acid or peptide fragment). This reversible crosslink underpins self-healing hydrogels, supramolecular polymers, stimuli-responsive materials and photochemical control. CB[8] is moderately water-soluble: warm to dissolve and filter while hot. Because ternary binding involves two sequential equilibria, determine binary and ternary constants separately.

Storage, Solubility and Handling Notes

  • Store sealed, dry and protected from light at room temperature; for long-term storage keep at 2–8 °C under dry conditions.
  • Cucurbituril powders are somewhat hygroscopic — reseal promptly after use and record the batch number and opening date.
  • Solubility tips: CB[7] and the modified series dissolve directly in water; for CB[6], dissolve first in formic acid or DMSO, then dilute into the target solvent system.
  • Filter stock host solutions and use them freshly prepared; for binding experiments record buffer composition, ionic strength and pH.
  • These materials are for scientific research use only and must not be used in humans, food, pharmaceutical manufacturing or clinical diagnostics.
  • Batch-specific purity, water content and spectral data are available on request before ordering.

Selection and further reading